QUESTION 1
1.1 A(2)
1.2 A(2)
1.3 B(2)
1.4 C(2)
1.5 A (2)
1.6 B(2)
1.7 A(2)
1.8 C(2)
1.9 A(2)
1.10 B(2) [20]
QUESTION 2
2.1 A series of organic molecules that can be described by the same general formula and where each member differs from the next by a CH2 group. (2)
2.2 2.2.1 Organic molecules with the same molecular formula, but different structural formula. (2)
2.2.2
(2)
2.2.3 Aldehydes (2)
2.2.4 3-Chlorobut-1-ene (2)
2.2.5
Methyl part | 1 mark |
|
Ethanoate part (functional group) | 1 mark |
|
(2)
2.3
2.3.1 Small organic molecules that can be covalently bonded to each other in a repeating pattern. (2)
2.3.2 2-Ethene (2)
2.3.3
QUESTION 3
3.1 CnH2n+2 (1)
3.2 (2)
3.3 Propanal (2)
3.4
3.4.1 Hydrogen bonds and London forces (1)
3.4.2 Van der Waals forces (London forces) or Induced dipole force (Any one) (1)
3.5 As the strength of the intermolecular forces become stronger (increases) then the vapour pressure will become lower (decrease) OR As the strength of intermolecular forces become weaker, then the vapour pressure will become higher (increase). (2)
3.6 Ethanoic acid.
QUESTION 4
4.1 Addition (reaction) Hydation (1)
4.2
4.3 2-bromo butane (2)
4.4
One mark for each reactant and product (3)
4.5
Butan-2-ol (3)
4.6 C4H8 + 6O2 → 4 CO2 + 4 H2O balance (3)
4.7 Hydrolysis (2) [16]
QUESTION 5
5.1
5.2 Temperature: 298 K or 25 °C
Concentration : 1 mol.dm-3 (2)
5.3
5.3.1 2 Cl- → Cl2 + 2e- (2)
5.3.2 Cu2+ + 2e- → Cu (2)
5.4 Electrolytic cell – Converts electrical energy to chemical energy. (2)
5.5 Q Reduction takes place (2)
5.6
5.6.1 Cu is a stronger reducing agent than Cl ions. Cu will be oxidised to Cu2+ ions resulting in the plate becoming eroded. (3)
5.6.2 Non-spontaneous (1) [16]
QUESTION 6
6.1 Galvanic Cell: Chemical energy is converted to electrical energy. (2)
6.2 External circuit or through the voltmeter. (2)
6.3 It maintains electrical neutrality OR It separates the two compartments so that they do not mix. (2)
6.4 Zn → Zn2+ + 2e- (2)
6.5 from Zn to Cu (1)
6.6 Zn + Cu2+ → Zn2+ + Cu (3)
6.7
6.8 It means they did not take the measurements at standard conditions where temperature is 298 K or 25 °C and concentration of 1 mol.dm-3. (3)
6.9
6.9.1 During solar construction, the following are identified as environmental threats:
6.9.2
QUESTION 7
7.1 The incident ray, the reflected ray and the normal to the surface all lie in the same plane and the angle of reflection ᶿr = angle of incidence ᶿi. (2)
7.2
7.2.1 Total internal reflection (1)
7.2.2 Refraction (1)
7.3
7.4
7.5
7.5.1 It is an angle of incidence in the denser medium such that the refracted rays just passes through the surface of separation of the two medium. (2)
7.5.2 24° (2)
7.6 A
7.7
7.7.1 Dispersion is when white light spreads into its component colours. (2)
7.7.2 Violet (blue region ) (1)
7.7.3 It has a higher frequency. The higher the frequency, the less the degree of refraction. (2) [19]
QUESTION 8
8.1 Refraction is the bending of light when it passes from one optical medium to another. (2)
8.2
8.3
8.3.1 20° (1)
8.3.2 41° (2)
8.4
8.4.1
8.4.2
QUESTION 9
9.1 It is a wave with a changing magnetic and electric field perpendicular to each other in the direction of propagation of the wave. (2)
9.2
9.3 They have a penetrating ability into the skin that can cause skin cancer. (2)
9.4 (5)
9.5 SMALLER THAN (1) [13]
TOTAL: 150